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Creating Black Gold: Alloys and Niello Processes


Question
hello Sir, yes i meant black color of gold. in the same way that is purple or green gold. are there any alloys where you need to add in order to get black color. i know nothing. i just got a request from my customer about black gold. they know nothing even i dont. its not about black hills gold but black color of gold. please let me know.

Answer
Bhupesh,
there is a process that is widely used in India that is called Niello, it is a mercury based process used to  give contrast against a high karat gold background. Perhaps that is what the  customer  is speaking about. It is  highly dangerous though and without experience I don't recommend  trying it unless you  can set  up  outdoors - the process itself isn't that hard, just that the elements  themselves  are dealy if  used improperly or inhaled- it would depend on the level of experience you qualify yourself as having as to wether or not to procedd inits lenghty expalination.
As for a  coloured gold alloy formula ther are a few new on the market "chocolate" and brown colourations that are  vapour deposited" and proprietary formulas.They wil eventually wear off. But to colour gold black the standard formula is:
platinum chloride in alcohol or  more  readily available, liver of sulphur painted hot onto the surface. Iodine will also work  but  you will have to  make some sample tiles to  get  between the blue range and black colouration  desired.All must be sealed with beeswax or light oil rubbed into the surface colorant. Permanance depends on  the piece and the person wearing it's body chemichals, perfumes,  cosmetics, etc.
There is another formula  but it too is quite toxic and without knowing what you are doing can be dealdly. Disposal of the remaining  solution is also an issue - as it must be  properly sealed and neutralized and is more of a hassle than  the  job will bring you in cost and labour and acquiring the chemicals if you don't have them on hand: Nonetheless, this formula can be applied to  copper, silver, brasses, in addition to gold:

120.0 g Sodium thiosulphate
Lead acetate 12.5 g
Distilled water 0.5 liters
you would mix that  and store it ina non metallic lidded vessel such as glass with a ground glass stopper to store.Immediately before use,  add 1.5 g citric acid- which renders the whole batch  spent. So to use a portion you would then calculate how much area you want to cover and  divide the stored solution  adding the  percentage of the 1.5 grams of citric acid necessary for the reaction to colour your piece..Remember to sela the colourant on with beeswax, oil or microcrystalline wax rubbed in well and  insure that after sealing you have thouroughly rinsed the item and  cleaned the parts  that  contact the skin as the lead content is  very absorbable through the skin.
 I really don't recommend your using it  but that is the standard formula anyway and I understand that  some customers don't care about the risks you take  in making it  or the risk  involved in wearing  it..So use your best judegment in   responding to your customer and charge an appropriate fee that covers the sheer  hassle and time it takes to assemble ingredients you may not have, asking and waiting for an answer through this service, and  the time it takes to fabricate and colour the item- all part of the total including your  shop's overhead and expenses and  ordering in supplies, etc...

I hope this answers your question.
Best regards, Ari