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Understanding Gold Melting & Refining: Calculating Yield & Loss


Question

Gold Bars Prior To Mel
Hello Dr I wonder if you could answer a question regarding the following. I recently melted together a bunch of 9ct gold scrap into a bar. I sent the drilling sample of the bar I melted to an assay office and was returned an assay of 37.5% which is what I expected. However I then took my very clean gold bars and sent it off for processing. They took both bars and melted them together however there was a 3% melt loss from the refining company. Is there a logical answer why I should loose nearly 55grams from this 9ct scrap gold bar that I melted? I trust the refining company implicitly but I need to know the scientific answer if there is one. Many thanks Tony

Answer
Hello Tony,
the answer is perhaps the copper alloy..if you  have 9ct gold it is less than 50%  fine  and as such  sending in a bar of "pure 9ct gold " means  you  sent in an alloy- without dissolving off the  copper in aqua regia
You sent them the alloy if I understand you correctly. If  I am not , you sent in a bar of pure gold and  the math  does not work,  however, the  refinery  usually does  not give a 100% return  on the  gold content, so  If I knew the refiners name I could look into their policies and  do some figuring based on that info.
Since you  are  scrapping 9ct. I  think this must  be the UK,  so  Cooksons or  any number of refineries should not have  given  a 37% loss on fine gold as  settlement.
If you will send me some more facts I will certainly try and figure out what happened. If you like send it to me off this forum to protect your self and not name any corporations outright  (vieuxcarrejewelers@gmail.com- will get the message to me confidentially).
Best regards, Ari